Rotational analysis of 6ν3 and 6ν3+ν2-ν2 bands of 14N2 16O from ICLAS spectra between 12760 and 12900 cm-1

نویسندگان

  • R. Milloud
  • Valeri P. Perevalov
  • S. A. Tashkun
  • Alain Campargue
  • V. I. Perevalov
چکیده

The absorption spectrum of nitrous oxide (N2O) has been recorded by Intracavity Laser Absorption Spectroscopy between 12760 and 12900 cm -1 . The rotational analysis led to an improved determination of the rovibrational parameters of the 6ν3 and 6ν3+ν2-ν2 bands of 14 N2 16 O. The high J rotational levels of the (00 0 6) and (01 1 6) upper states were found perturbed by an anharmonic interaction. Line intensity values of the 6ν3 band are provided and the main effective dipole moment parameter has been determined.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Preliminary analysis of CH3D from 3250 to 3700 cm(-1)

The infrared spectrum of CH3D from 3250 to 3700 cm =1 was studied for the rst time to assign transitions involving the ν2+ν3, ν2+ν5, ν2+ν6, ν3+2ν6 and 3ν6 vibrational states. Line positions and intensities were measured at 0.011 cm resolution using Fourier transform spectra recorded at Kitt Peak with isotopically enriched samples. Some 2852 line positions (involving over 900 upper state levels)...

متن کامل

Infrared spectroscopy of the ν2 band of the water monomer and small water clusters (H2O)n=2,3,4 in helium droplets.

We have recorded infrared spectra in the frequency range of the ν2 band of water monomer and water clusters in superfluid helium droplets. In order to be able to map the chemically important fingerprint range, we have used an IR quantum cascade laser as a radiation source. We were able to observe three ro-vibrational transitions of the water monomer between 1590 and 1670 cm(-1). The lines were ...

متن کامل

2d Correlation Spectroscopy and Its Application in Vibrational Spectroscopy Using Matlab

Two dimensional correlation spectroscopy is a powerfull tool for spectral analysis. It is able to reveal correlations between spectral changes and to deconvolve overlapping peaks. It is easily applicable in a study of biomolecules. Here presented program was created for easy accessibility of all necessary operations. Presented algorithm was deeply tested on regular spectra as well as on a spect...

متن کامل

John Wiley & Sons Raman spectroscopy of halogen containing carbonates

Raman spectroscopy complimented with infrared spectroscopy has been used to study a series of selected natural halogenated carbonates from different origins including bastnasite, parisite and northupite. The position of CO3 symmetric stretching vibration varies with mineral composition. An additional band for northupite at 1107 cm is observed. Raman spectra of bastnasite, parisite and northupit...

متن کامل

Photoelectron spectroscopy of the thiazate (NSO-) and thionitrite (SNO-) isomer anions.

Anion photoelectron spectra of the thiazate (NSO-) and thionitrite (SNO-) isomers are reported. The NSO- photoelectron spectrum showed several well-resolved vibronic transitions from the anion to the NSO radical neutral. The electron affinity of NSO was determined to be 3.113(1) eV. The fundamental vibrational frequencies of NSO were measured and unambiguously assigned to be 1202(6) cm-1 (ν1, a...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2017